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The first model for the distribution of ions near the surface of a metal electrode was devised by Helmholtz in 1874. He envisaged two parallel sheets of charges of opposite sign located one on the metal surface and the other on the solution side, a few nanometers away, exactly as in the case of a parallel plate capacitor. The rigidity of such a model was allowed for by Gouy and Chapman inde pendently, by considering that ions in solution are subject to thermal motion so that their distribution from the metal surface turns out diffuse. Stern recognized that ions in solution do not behave as point charges as in the Gouy-Chapman treatment, and let the center of the ion charges reside at some distance from the metal surface while the distribution was still governed by the Gouy-Chapman view. Finally, in 1947, D. C. Grahame transferred the knowledge of the struc ture of electrolyte solutions into the model of a metal/solution interface, by en visaging different planes of closest approach to the electrode surface depending on whether an ion is solvated or interacts directly with the solid wall. Thus, the Gouy-Chapman-Stern-Grahame model of the so-called electrical double layer was born, a model that is still qualitatively accepted, although theoreti cians have introduced a number of new parameters of which people were not aware 50 years ago. Electrochemical Supercapacitors : Scientific Fundamentals Scientific Fundamentals and Technological Applications B E Conway Electrochemical Supercapacitors: Scientific Fundamentals and Technological Electrochemical Supercapacitors - Springer Scientific Fundamentals and Technological Applications Electrochemical Supercapacitors Scientific Fundamentals and Technological Applications Electrochemical Super Capacitors Scientific Fundamentals Scientific Fundamentals and Technological Applications Electrochemical supercapacitors scientific technological applications I BE Conway p em Electrochemical Supercapacitors - Springer Electrochemical Supercapacitors Scientific Fundamentals and Technological Applications 8 E count of the electrochemical science and technology of these FUNDAMENTALS OF ELECTROCHEMICAL CAPACITOR DESIGN AND OPERATION in promotional literature as supercapacitors In many practical applications therefore electrochemical Scientific Fundamentals and Technological Electrochemical Supercapacitors : Scientific Fundamentals Buy Electrochemical Supercapacitors: Scientific Fundamentals and Fundamentals and Technological Applications Supercapacitors: Scientific Fundamentals Electrochemical Supercapacitors: Scientific Fundamentals Buy Electrochemical Supercapacitors: Scientific Fundamentals and Technological Applications on FREE SHIPPING on qualified orders Electrochemical Supercapacitors - Scientific Fundamentals Electrochemical Supercapacitors Scientific Fundamentals and Technological Applications The Electrochemical Behavior of Ruthenium Oxide Electrochemical Supercapacitors: Scientific Fundamentals Electrochemical Supercapacitors: Scientific Fundamentals and Technological Applications (9780306457364) Electrochemical Supercapacitors: Scientific Conway BE Electrochemical supercapacitors Scientific Conway BE Electrochemical supercapacitors Scientific fundamentals and technological applications Kluwer Academic Plenum Publishers New York 1999 698
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